Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 638, Issue 11, Pages 1784-1786Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201200287
Keywords
Phosphorus; Sulfur: Chlorine; Reaction mechanisms; Intermediates
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Triphenylphosphine reacts with thionyl chloride to give [Ph3PCl]Cl, Ph3PO and Ph3PS the formation of the anions S(O)Cl and SCl being discussed; the crystal structure of [Ph3PCl]Cl center dot S(O)Cl2 is reported.
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