Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 638, Issue 6, Pages 1039-1041Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.201200004
Keywords
Carbonate-bridging; Rhodium; CO2 fixation; NMR spectroscopy; IR spectroscopy
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Funding
- National Natural Science Foundation of China [20971058]
- Fundamental Research Funds for Central Universities [JUSRP 11105]
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A carbonate-bridged rhodium(III) dimeric complex of formula mu-CO3-[(ppy)2Rh]2, (ppy = 2-phenylpyridine) was synthesized and characterized by IR and 1H NMR spectroscopy as well as X-ray diffraction. The bridging carbonate ion presumably originates from the capture of CO2 in air deduced on a series of control experiments, which may have valuable implications for the study of fixation of CO2. The luminescent and thermal properties of this complex were also investigated.
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