Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 634, Issue 10, Pages 1645-1647Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200800153
Keywords
perovskite analogues; solid-state chemistry; barium chromium uranium sulfide
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The compound Ba4Cr2US9, which crystallizes in space group P321, consists of'one-dinlensional (1)(infinity)[Cr2US98-] chains separated by Ba2+ cations. Each one-dimensional chain comprises face-sharing CrS6 octalledra and US6 trigonal prisms in the sequence oct oct tp oct oct tp with the U and Cr centers in a linear chain parallel to [001].
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