Journal
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Volume 634, Issue 5, Pages 892-894Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/zaac.200700517
Keywords
coordination chemistry; cuprates; Jahn-Teller distortion; nitratocuprates(II); crystal structures
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The reaction of methylammonium nitrate and copper(H) nitrate pentahemihydrate in concentrated nitric acid yields the novel bis(monomethylammonium) tetranitratocuprate(II). By evaporation of the nitric acid at elevated temperatures single crystals suitable for crystal structure analysis by X-ray diffraction were obtained. The crystal structure shows a clear Jahn-Teller distortion in the octahedral nitratocuprate anion.
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