4.5 Article

Poly(acrylic acid) modifying bentonite with in-situ polymerization for removing lead ions

Journal

WATER SCIENCE AND TECHNOLOGY
Volume 65, Issue 8, Pages 1383-1391

Publisher

IWA PUBLISHING
DOI: 10.2166/wst.2012.011

Keywords

adsorption; bentonite adsorbent; isotherm; kinetics; lead ions; poly(acrylic acid)/bentonite composites

Funding

  1. NSFC [20964002]
  2. Gansu Sci & Techn Support Project [1011GKCA017]
  3. Gansu Univ [2010-176]

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In this paper, a new kind of poly(acrylic acid) modified clay adsorbent, the poly(acrylic acid)/bentonite composite (PAA/HB) was prepared by in-situ polymerization, and utilized to remove lead(II) ions from solutions. The maximum adsorption of adsorbent is at pH 5 for metal ions, whereas the adsorption starts at pH 2. The effects of contact time (5-60 min), initial concentration of metal ions (200-1,000 mg/L) and adsorbent dosage (0.04-0.12 g/100 mL) have been reported in this article. The experimental data were investigated by means of kinetic and equilibrium adsorption isotherms. The kinetic data were analyzed by the pseudo-first-order and pseudo-second-order equation. The experimental data fitted the pseudo-second-order kinetic model very well. Langmuir and Freundlich isotherms were tried for the system to better understand the adsorption isotherm process. The maximal adsorption capacity of the lead(II) ions on the PAA/HB, as calculated from the Langmuir model, was 769.2 mg/g. The results in this study indicated that PAA/HB was an attractive candidate for removing lead(II) (99%).

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