4.6 Article

Efficient Removal of Anionic and Cationic Dyes from an Aqueous Solution Using Pullulan-graft-Polyacrylamide Porous Hydrogel

Journal

WATER AIR AND SOIL POLLUTION
Volume 225, Issue 11, Pages -

Publisher

SPRINGER INTERNATIONAL PUBLISHING AG
DOI: 10.1007/s11270-014-2177-5

Keywords

Dye adsorption; Porous hydrogel; Pullulan; Acrylamide; Water treatment

Ask authors/readers for more resources

A pullulan-graft-polyacrylamide porous hydrogel was prepared by radical polymerization in the presence of a crosslinking agent (N,N'-methylenebisacrylamide). Then, the swelling behavior of the hydrogel and the kinetics of swelling were investigated. The novel synthesized hydrogel was used as an adsorbent for removal of dyes from aqueous solutions. In this study, methylene blue (MB) and reactive blue 2 (RB) were selected as representative cationic and anionic dyes, respectively. The synthesized porous hydrogel exhibited excellent adsorption ability for both dyes. Various experimental conditions affecting the dye adsorption were explored to achieve maximum removal of both dye molecules. In addition, kinetic, thermodynamic, and adsorption isotherm models were employed to describe the dye adsorption process. The results indicated that the prepared hydrogel is an efficient adsorbent for dyes and possesses the ability to be regenerated without losing its original activity and stability for water treatment applications.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.6
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Engineering, Chemical

Application of 3D Bioprinters for Dental Pulp Regeneration and Tissue Engineering (Porous architecture)

Pedram Iranmanesh, Athena Ehsani, Abbasali Khademi, Azadeh Asefnejad, Sheyda Shahriari, Maryam Soleimani, Mazyar Ghadiri Nejad, Saeed Saber-Samandari, Amirsalar Khandan

Summary: 3D printing technique is well-known for producing porous scaffolds or special three-dimensional structures layer by layer. Integration of different technologies and materials can enhance the properties of 3D tissue engineering scaffolds. Various tissue engineering strategies include cell-based, factor-based, and scaffold-based approaches.

TRANSPORT IN POROUS MEDIA (2022)

Article Polymer Science

Antimicrobial activities of synthetic water-soluble ethylenediamine-epichlorohydrin-based oligomers

Faisal Suleiman Mustafa, Akeem Adeyemi Oladipo, Mustafa Gazi

Summary: The study employed a two-step simple method to synthesize new oligomers EEO and EETO with significant antibacterial activity. Analysis showed that both oligomers exhibit good antibacterial effects against S. aureus and are harmless to cells.

POLYMER BULLETIN (2022)

Article Materials Science, Composites

Experimental and numerical research on healing performance of reinforced microcapsule-based self-healing polymers using nanoparticles

Reza Barbaz-Isfahani, Saeed Saber-Samandari, Manouchehr Salehi

Summary: This study investigates the effect of enhancing multicore microcapsules with various nanoparticles on the healing efficiency of microcapsule-based self-healing polymers. The results show that increasing the volume fraction of microcapsules can enhance the healing efficiency, while increasing the strength of microcapsules can decrease the healing efficiency.

JOURNAL OF REINFORCED PLASTICS AND COMPOSITES (2023)

Article Electrochemistry

Hydroxyapatite nanoparticles coating on Ti-6Al-4V substrate using plasma spray method

P. Bagheri, S. Saber-Samandari, A. Sadeghi, S. Akhtarian, A. Doostmohammadi

Summary: In this research, hydroxyapatite powder particles were coated on a Ti-6Al-4V alloy substrate using the plasma spraying method. The study aimed to take advantage of titanium's mechanical properties and hydroxyapatite's biological properties to create bone implants. Preheating the substrate was found to improve adhesion and reduce residual stress, however, it also resulted in the formation of an amorphous phase in the coating, leading to weaker mechanical properties.

TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING (2023)

Article Engineering, Biomedical

Synthesis and characterization of a novel hydrogel based on carboxymethyl chitosan/sodium alginate with the ability to release simvastatin for chronic wound healing

Fatemeh Karami, Saeed Saber-Samandari

Summary: In this study, a multifunctional wound dressing based on carboxymethyl chitosan/sodium alginate hydrogel containing a nanostructured lipid carrier (NLC) was prepared. The dressing showed appropriate properties for absorbing exudates and maintaining wound moisture. It displayed excellent antibacterial activity and high biocompatibility, and had the ability to release the loaded drug slowly over a prolonged period of time. The results suggest that this novel nanocomposite could be a promising candidate as a wound dressing for treating various chronic wounds in skin tissues.

BIOMEDICAL MATERIALS (2023)

Article Materials Science, Multidisciplinary

Alginate carrier as a controlled thymol delivery system: Effect of particle size

Azin Rashidy Ahmady, Kavoos Razmjooee, Vida Nazar, Saeed Saber-Samandari

Summary: This study compared alginate microparticles and nanoparticles as thymol delivery systems. The results showed that thymol-loaded alginate nanoparticles released thymol in a more sustainable and controllable manner, and both carriers exhibited good cell viability and antibacterial properties.

MATERIALS CHEMISTRY AND PHYSICS (2023)

Article Chemistry, Physical

Capsaicin-loaded alginate nanoparticles embedded polycaprolactone- chitosan nanofibers as a controlled drug delivery nanoplatform for anticancer activity

Azin Rashidy Ahmady, Atefeh Solouk, Saeed Saber-Samandari, Somaye Akbari, Hadi Ghanbari, Bogumil E. Brycki

Summary: Nano-in-nano delivery technique is explored to address the limitations of most nanostructures used for drug delivery. This study investigated the release behavior of a novel nanoparticles-in-nanofibers delivery system composed of capsaicin-loaded alginate nanoparticles embedded in polycaprolactone-chitosan nanofiber mats. The results showed that embedding capsaicin-loaded alginate nanoparticles in polycaprolactone-chitosan nanofibers prolonged capsaicin release and effectively inhibited the proliferation of MCF-7 human breast cells.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2023)

Article Materials Science, Composites

Damage evolution of polymer matrix composites reinforced by nanoparticles modified under the three-point bending test by acoustic emission methods

Sina Shayanfar, Majid Nikkhah, Saeed Saber-Samandari, Manouchehr Salehi

Summary: This study aimed to investigate the behavior and failure resistance of composite materials, as well as the effect of nanoparticles on their flexural properties. Different weight percentages of nano-clay and nano-silica were added to a hybrid composite to analyze their effect. The addition of nanoparticles up to 1 wt.% improved flexural strength and modulus, and the samples containing nanoparticles were more resistant to damage growth.

JOURNAL OF COMPOSITE MATERIALS (2023)

Article Materials Science, Multidisciplinary

Fabrication and characterization of a newly designed nanocomposite scaffold based on a gelatin network comprising multi-walled carbon nanotube and sodium montmorillonite nanoparticles

Saeed Saber-Samandari, Davood Toghraie

Summary: A new nanocomposite scaffold was successfully synthesized in this study, which exhibited high porosity and the ability to induce bone-like apatite formation by incorporating carbon nanotubes and montmorillonite nanoparticles in a gelatin network. After soaking in simulated body fluid for 14 days, the scaffold surface successfully deposited Ca2+, CO32-, and PO43- ions. In addition, the introduction of nanoparticles significantly improved the mechanical properties of the scaffold and reduced the enzymatic degradation rate. The scaffold showed good biocompatibility and high photothermal efficiency, making it suitable for tissue engineering applications.

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS (2023)

Review Nanoscience & Nanotechnology

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

Akeem Adeyemi Oladipo, Saba Derakhshan Oskouei, Mustafa Gazi

Summary: Increasing levels of antibiotics and hormones in the environment and food samples are concerning. Opto-electrochemical sensors, specifically using metal-organic frameworks (MOFs), have shown promise for detecting and monitoring these compounds due to their low cost, portability, and sensitivity. This review critically examines the capabilities of electrochemical and luminescent MOF sensors for detecting antibiotics and hormones in various samples, and discusses the challenges, recent advances, and future directions for developing stable and high-performance MOFs as commercially viable sensor materials.

BEILSTEIN JOURNAL OF NANOTECHNOLOGY (2023)

Article Multidisciplinary Sciences

A comprehensive investigation of the low-velocity impact response of enhanced GFRP composites with single and hybrid loading of various types of nanoparticles

Reza Barbaz-Isfahani, Hooman Dadras, Saeed Saber-Samandari, Alireza Taherzadeh-Fard, Gholamhossein Liaghat

Summary: This study investigates the effects of incorporating various types of nanoparticles, both singularly and in hybrid form, on the low-velocity impact (LVI) response of glass fiber reinforced polymer (GFRP) composites. The experimental results reveal that specimens with a single loading of MWCNT or nano-clay have a lower maximum contact force compared to pure specimens with fully rebounding behavior. Furthermore, incorporating more MWCNTs results in stiffer behavior and more brittleness.

HELIYON (2023)

Article Biochemistry & Molecular Biology

Alginate-based porous polyHIPE for removal of single and multi-dye mixtures: Competitive isotherm and molecular docking studies

Hoda Ansari, Akeem Adeyemi Oladipo, Mustafa Gazi

Summary: A novel hydrophilic porous alginate-based polyHIPE (AGA) was synthesized and used as an adsorbent for the removal of methylene blue (MB) dye. The adsorption efficiency of AGA was affected by the presence of Cu2+ ions and solution salinity. The experimental data showed good fit with extended Langmuir and Sheindorf-Rebhun-Sheintuch models in a multi-dye system.

INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES (2023)

Article Materials Science, Composites

On the mechanical properties and vibrational characteristics of the nanoparticle-reinforced composite cylindrical panels in the acidic environment: Numerical and experimental investigation

Maysam Alinia, Saeed Saber-Samandari, Seyyed Ali Sadough Vanini

Summary: The purpose of this study is to investigate the effects of adding nano-clay and nano-silica particles on the vibrational characteristics of composite cylindrical panels in corrosive environments. The study finds that adding nanoparticles can significantly improve the mechanical properties and natural frequencies of the composites, with nano-clay being more effective.

JOURNAL OF REINFORCED PLASTICS AND COMPOSITES (2023)

Article Materials Science, Multidisciplinary

Investigating the effect of external force on the collision of an iron bullet with shear-thickening fluid nanocomposites using molecular dynamics simulation

Guoqi Guo, As'ad Alizadeh, Saeed Saber-Samandari, Maboud Hekmatifar, Jun Li, Mohammed Al-Bahrani, Navid Nasajpour-Esfahani, Mahmoud Shamsborhan, Davood Toghraie

Summary: Bullets are used as projectiles in firearms for various purposes. They also have industrial applications such as precision drilling, cutting, and shaping of hard materials. Different industries, such as automotive and aerospace, use fibers and fabrics with high toughness and tensile strength to resist impact and projectiles. In a recent study, the impact of external force on the strength of Kevlar nanofibers reinforced with silicon dioxide nanoparticles and ethylene glycol was investigated. The findings suggest that optimizing the external force is crucial for an effective collision process.

JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T (2023)

Article Materials Science, Multidisciplinary

Effect of corrosive environment on mechanical properties of polymer-based nanocomposite: Analytical and experimental study

Farshad Rahmani, Reza Barbaz-Isfahani, Saeed Saber-Samandari, Manouchehr Salehi

Summary: The aim of this study is to investigate the critical buckling force of a sandwich structure with the addition of nanoparticles to composite faces in an acidic environment. The addition of 3 wt% nanoclay shows better performance in improving the durability of the structure against changes in the length and mass of the composite specimens. The immersion in 5% sulfuric acid for 30 days significantly reduces the critical buckling force of composite sandwiches.

MATERIALS TODAY COMMUNICATIONS (2023)

No Data Available