Article
Chemistry, Multidisciplinary
Gulenay Uzum, Busra Akin Ozmen, Ebru Tekneci Akgul, Erdem Yavuz
Summary: Adsorbents with interconnected porous structure were produced using a high internal phase emulsion (HIPE) method. The adsorption performances were enhanced by hyper-cross-linking and surface tailoring, and the adsorbents showed potential for reusability through treatment with an acidic solution.
Article
Chemistry, Applied
Xing-Hao Du, Zhiyong Jiang, Zhipeng Liu, Chao Xu
Summary: Conjugated porous polymers (CPPs) are a new family of functional porous materials with tuneable porosities and molecular architectures, showing great potentials in adsorption, light harvesting, and catalysis applications. This study describes the incorporation of strong visible-light absorbing BODIPY molecules into the skeleton of CPPs, resulting in CPPs with integrated properties of high surface area, hierarchical porous structures, and strong visible-light absorption. The obtained CPPs demonstrated relatively high adsorption capacity and high photocatalytic degradation efficiency towards organic dyes, with mechanism studies revealing the generation of singlet oxygen species as the main driving force for the dye degradation.
MICROPOROUS AND MESOPOROUS MATERIALS
(2022)
Article
Engineering, Environmental
Zhiying Wu, Ping Zhang, Haihui Zhang, Xiaotian Li, Yunfeng He, Peiwu Qin, Canhui Yang
Summary: A cost-effective, stable, and recyclable adsorbent with high adsorption capacity and rapid adsorption kinetics is developed by synthesizing a tough porous nanocomposite hydrogel using biochar nanoparticles and interconnected pores. The hydrogel provides mechanical strength, biochar provides adsorption sites, and interconnected pores expedite solvent transport. The hydrogel shows enhanced adsorption performance and mechanical robustness, making it promising for water treatment applications.
JOURNAL OF HAZARDOUS MATERIALS
(2022)
Article
Green & Sustainable Science & Technology
S. Lamkhao, S. Tandorn, G. Rujijanagul, C. Randorn
Summary: In this study, a practical use-suited highly porous zinc oxide/polyacrylamide hydrogel composite photocatalyst was successfully synthesized and applied for the treatment of real wastewater. The results showed that the porous ZnO/PAM composite exhibited effective removal of color, BOD, and COD in both canal and industrial wastewater. It also demonstrated good long-term stability and recycling performance with high degradation efficiency even after 50 degradation cycles. The findings suggest that the highly porous zinc oxide/polyacrylamide hydrogel composite has great potential for use in real wastewater treatment.
MATERIALS TODAY SUSTAINABILITY
(2023)
Article
Chemistry, Physical
Hairong Huang, Zhenying Liu, Jianhua Yun, Hu Yang, Zhen-liang Xu
Summary: The study involved the preparation of Laponite (Lap) hydrogel capsules by dropwise addition of Lap solution to an aluminum salt solution. The capsules showed good stability, high adsorption capacities for cationic dyes, and low affinity for anionic dyes. Additionally, they demonstrated the ability to be repeatedly used for dye removal and exhibited good selectivity for specific dyes.
APPLIED CLAY SCIENCE
(2021)
Article
Engineering, Environmental
Buse Sonmez, Ayse Nur Celikkol
Summary: Pullulan-graft-poly(AA-co-AAm) hydrogel showed the highest swelling capacity and was efficient in adsorbing cadmium(II) ions. The prepared hydrogels demonstrated good adsorption-desorption cycles and reusability, making them suitable candidates for heavy metal ion removal applications.
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
(2021)
Article
Environmental Sciences
Tao Xue, Feifei Shao, Han Miao, Xinxin Li
Summary: Dye wastewater from industries is causing serious environmental problems. Adsorption technology has emerged as a promising method for dye wastewater treatment in the past decade. We developed two kinds of magnetic porous adsorbents (HSF and HSVF) with different specific surface areas and activity sites. Both adsorbents showed excellent performance in terms of dye adsorption capacity, especially HSVF. The adsorption kinetics and isotherms were further studied and compared, revealing that introducing strong active sites can improve adsorption capacity and rate. This research highlights the significance of adsorption technology for treating dye wastewater.
ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
(2023)
Article
Chemistry, Physical
Wei Wang, Mengbo Fan, Jiaming Ni, Weijun Peng, Yijun Cao, Huiyong Li, Yukun Huang, Guixia Fan, Yunliang Zhao, Shaoxain Song
Summary: This study investigates the use of Montmorillonite nanosheet/poly(acrylamide-co-acrylic acid)/sodium alginate hydrogel beads as an adsorbent for dye effluent. The hydrogel beads demonstrate multilayer and heterogeneous adsorption of methylene blue and exhibit excellent dynamic adsorption performance compared to traditional adsorbents. These findings suggest that the hydrogel beads have great potential for practical applications in the treatment of dye effluent.
APPLIED CLAY SCIENCE
(2022)
Article
Engineering, Chemical
Chao Wang, Guanlin Zhou, Xiaosong Wang, Jinguo Liu, Dong Li, Chengwei Wu, Wei Zhang
Summary: The PVA-TiO2 composite hydrogel membrane with high mechanical properties and photocatalytic ability was prepared by adding DMSO, TiO2, and Na2CO3 to PVA using the freeze-thaw cycle method. The optimized membrane exhibited the highest tensile strength reported for its kind and a significant dye removal rate after nature light treatment.
SEPARATION AND PURIFICATION TECHNOLOGY
(2021)
Article
Environmental Sciences
Hamid Safarzadeh, Seyed Jamaleddin Peighambardoust, Seyed Hamed Mousavi, Rauf Foroutan, Reza Mohammadi, Seyed Hadi Peighambardoust
Summary: The performance of poly(MAA-co-AAm)/Cl30B nanocomposite hydrogel in adsorbing methylene blue dye was investigated. The incorporation of Cloisite 30B nanoclays improved the adsorption efficiency. The results showed that the nanocomposite hydrogel had higher adsorption capacity and followed pseudo-first-order kinetic model.
ENVIRONMENTAL RESEARCH
(2022)
Article
Green & Sustainable Science & Technology
Chan Juan Li, Yao Jun Zhang, Hao Chen, Pan Yang He, Qian Meng
Summary: In this paper, a cost-effective hierarchical pore geopolymer based on solid waste was synthesized and showed excellent adsorption properties for removing methylene blue dye from wastewater. The acid-treated geopolymer particles exhibited a high specific surface area and microporosity, providing abundant adsorption sites for the dye. The optimal geopolymer adsorbent achieved a high adsorption efficiency and removal efficiency, and showed good regeneration performance and selectivity towards cationic dyes.
JOURNAL OF CLEANER PRODUCTION
(2022)
Article
Environmental Sciences
Sevda Pashaei-Fakhri, Seyed Jamaleddin Peighambardoust, Rauf Foroutan, Nasser Arsalani, Bahman Ramavandi
Summary: The study synthesized AM-SA and AM-GO-SA hydrogels successfuly and applied them for CV dye removal. The experimental results showed that adsorption efficiency is more dependent on pH, and the nanocomposite hydrogel has better adsorption capacity for CV dye.
Article
Polymer Science
Zhi Chen, Xia Song, Wilson Wee Mia Soh, Yuting Wen, Jingling Zhu, Miao Zhang, Jun Li
Summary: In this study, a magnetic composite hydrogel was developed for efficient removal of dye molecules from water. The synthesized magnetic hydrogel showed excellent performance in dye removal and could be reused multiple times, demonstrating great potential for wastewater treatment.
Article
Engineering, Chemical
Jia Xin Yap, C. P. Leo, Derek Juinn Chieh Chan, Nazlina Haiza Mohd Yasin, Mohd Shaiful Sajab
Summary: Water pollution requires sustainable materials for green treatment solutions. This study successfully extracted nanocellulose from microalgae through alkaline treatment, bleaching, and hydrolysis without TEMPO-mediated oxidation. The effects of acid concentration on nanocellulose properties were studied and the maximum yield was achieved using sulphuric acid with a concentration of 60%(v/v). The extracted microalgae nanocellulose was incorporated into carboxymethyl cellulose/sodium alginate beads, significantly increasing methylene blue adsorption capacity and achieving a high dye removal percentage.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Engineering, Multidisciplinary
Fereshte Hassanzadeh-Afruzi, Mohadeseh Forouzandeh-Malati, Fatemeh Ganjali, Mohammad Mehdi Salehi, Ali Maleki, Ehsan Nazarzadeh Zare
Summary: In this study, a kappa-carrageenan-grafted-poly(acrylamide)/Fe3O4-GO adsorbent was successfully prepared and characterized. The results showed that the adsorbent exhibited superparamagnetic behavior and a semi-crystalline structure, with improved surface area and porosity due to the incorporation of graphene oxide. The adsorption experiments demonstrated high adsorption capacity and efficient adsorption kinetics for the drug CPFX. Furthermore, the prepared adsorbent showed good retrievability and reusability.
ALEXANDRIA ENGINEERING JOURNAL
(2023)
Article
Engineering, Chemical
Pedram Iranmanesh, Athena Ehsani, Abbasali Khademi, Azadeh Asefnejad, Sheyda Shahriari, Maryam Soleimani, Mazyar Ghadiri Nejad, Saeed Saber-Samandari, Amirsalar Khandan
Summary: 3D printing technique is well-known for producing porous scaffolds or special three-dimensional structures layer by layer. Integration of different technologies and materials can enhance the properties of 3D tissue engineering scaffolds. Various tissue engineering strategies include cell-based, factor-based, and scaffold-based approaches.
TRANSPORT IN POROUS MEDIA
(2022)
Article
Polymer Science
Faisal Suleiman Mustafa, Akeem Adeyemi Oladipo, Mustafa Gazi
Summary: The study employed a two-step simple method to synthesize new oligomers EEO and EETO with significant antibacterial activity. Analysis showed that both oligomers exhibit good antibacterial effects against S. aureus and are harmless to cells.
Article
Materials Science, Composites
Reza Barbaz-Isfahani, Saeed Saber-Samandari, Manouchehr Salehi
Summary: This study investigates the effect of enhancing multicore microcapsules with various nanoparticles on the healing efficiency of microcapsule-based self-healing polymers. The results show that increasing the volume fraction of microcapsules can enhance the healing efficiency, while increasing the strength of microcapsules can decrease the healing efficiency.
JOURNAL OF REINFORCED PLASTICS AND COMPOSITES
(2023)
Article
Electrochemistry
P. Bagheri, S. Saber-Samandari, A. Sadeghi, S. Akhtarian, A. Doostmohammadi
Summary: In this research, hydroxyapatite powder particles were coated on a Ti-6Al-4V alloy substrate using the plasma spraying method. The study aimed to take advantage of titanium's mechanical properties and hydroxyapatite's biological properties to create bone implants. Preheating the substrate was found to improve adhesion and reduce residual stress, however, it also resulted in the formation of an amorphous phase in the coating, leading to weaker mechanical properties.
TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING
(2023)
Article
Engineering, Biomedical
Fatemeh Karami, Saeed Saber-Samandari
Summary: In this study, a multifunctional wound dressing based on carboxymethyl chitosan/sodium alginate hydrogel containing a nanostructured lipid carrier (NLC) was prepared. The dressing showed appropriate properties for absorbing exudates and maintaining wound moisture. It displayed excellent antibacterial activity and high biocompatibility, and had the ability to release the loaded drug slowly over a prolonged period of time. The results suggest that this novel nanocomposite could be a promising candidate as a wound dressing for treating various chronic wounds in skin tissues.
BIOMEDICAL MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Azin Rashidy Ahmady, Kavoos Razmjooee, Vida Nazar, Saeed Saber-Samandari
Summary: This study compared alginate microparticles and nanoparticles as thymol delivery systems. The results showed that thymol-loaded alginate nanoparticles released thymol in a more sustainable and controllable manner, and both carriers exhibited good cell viability and antibacterial properties.
MATERIALS CHEMISTRY AND PHYSICS
(2023)
Article
Chemistry, Physical
Azin Rashidy Ahmady, Atefeh Solouk, Saeed Saber-Samandari, Somaye Akbari, Hadi Ghanbari, Bogumil E. Brycki
Summary: Nano-in-nano delivery technique is explored to address the limitations of most nanostructures used for drug delivery. This study investigated the release behavior of a novel nanoparticles-in-nanofibers delivery system composed of capsaicin-loaded alginate nanoparticles embedded in polycaprolactone-chitosan nanofiber mats. The results showed that embedding capsaicin-loaded alginate nanoparticles in polycaprolactone-chitosan nanofibers prolonged capsaicin release and effectively inhibited the proliferation of MCF-7 human breast cells.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Materials Science, Composites
Sina Shayanfar, Majid Nikkhah, Saeed Saber-Samandari, Manouchehr Salehi
Summary: This study aimed to investigate the behavior and failure resistance of composite materials, as well as the effect of nanoparticles on their flexural properties. Different weight percentages of nano-clay and nano-silica were added to a hybrid composite to analyze their effect. The addition of nanoparticles up to 1 wt.% improved flexural strength and modulus, and the samples containing nanoparticles were more resistant to damage growth.
JOURNAL OF COMPOSITE MATERIALS
(2023)
Article
Materials Science, Multidisciplinary
Saeed Saber-Samandari, Davood Toghraie
Summary: A new nanocomposite scaffold was successfully synthesized in this study, which exhibited high porosity and the ability to induce bone-like apatite formation by incorporating carbon nanotubes and montmorillonite nanoparticles in a gelatin network. After soaking in simulated body fluid for 14 days, the scaffold surface successfully deposited Ca2+, CO32-, and PO43- ions. In addition, the introduction of nanoparticles significantly improved the mechanical properties of the scaffold and reduced the enzymatic degradation rate. The scaffold showed good biocompatibility and high photothermal efficiency, making it suitable for tissue engineering applications.
MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS
(2023)
Review
Nanoscience & Nanotechnology
Akeem Adeyemi Oladipo, Saba Derakhshan Oskouei, Mustafa Gazi
Summary: Increasing levels of antibiotics and hormones in the environment and food samples are concerning. Opto-electrochemical sensors, specifically using metal-organic frameworks (MOFs), have shown promise for detecting and monitoring these compounds due to their low cost, portability, and sensitivity. This review critically examines the capabilities of electrochemical and luminescent MOF sensors for detecting antibiotics and hormones in various samples, and discusses the challenges, recent advances, and future directions for developing stable and high-performance MOFs as commercially viable sensor materials.
BEILSTEIN JOURNAL OF NANOTECHNOLOGY
(2023)
Article
Multidisciplinary Sciences
Reza Barbaz-Isfahani, Hooman Dadras, Saeed Saber-Samandari, Alireza Taherzadeh-Fard, Gholamhossein Liaghat
Summary: This study investigates the effects of incorporating various types of nanoparticles, both singularly and in hybrid form, on the low-velocity impact (LVI) response of glass fiber reinforced polymer (GFRP) composites. The experimental results reveal that specimens with a single loading of MWCNT or nano-clay have a lower maximum contact force compared to pure specimens with fully rebounding behavior. Furthermore, incorporating more MWCNTs results in stiffer behavior and more brittleness.
Article
Biochemistry & Molecular Biology
Hoda Ansari, Akeem Adeyemi Oladipo, Mustafa Gazi
Summary: A novel hydrophilic porous alginate-based polyHIPE (AGA) was synthesized and used as an adsorbent for the removal of methylene blue (MB) dye. The adsorption efficiency of AGA was affected by the presence of Cu2+ ions and solution salinity. The experimental data showed good fit with extended Langmuir and Sheindorf-Rebhun-Sheintuch models in a multi-dye system.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2023)
Article
Materials Science, Composites
Maysam Alinia, Saeed Saber-Samandari, Seyyed Ali Sadough Vanini
Summary: The purpose of this study is to investigate the effects of adding nano-clay and nano-silica particles on the vibrational characteristics of composite cylindrical panels in corrosive environments. The study finds that adding nanoparticles can significantly improve the mechanical properties and natural frequencies of the composites, with nano-clay being more effective.
JOURNAL OF REINFORCED PLASTICS AND COMPOSITES
(2023)
Article
Materials Science, Multidisciplinary
Guoqi Guo, As'ad Alizadeh, Saeed Saber-Samandari, Maboud Hekmatifar, Jun Li, Mohammed Al-Bahrani, Navid Nasajpour-Esfahani, Mahmoud Shamsborhan, Davood Toghraie
Summary: Bullets are used as projectiles in firearms for various purposes. They also have industrial applications such as precision drilling, cutting, and shaping of hard materials. Different industries, such as automotive and aerospace, use fibers and fabrics with high toughness and tensile strength to resist impact and projectiles. In a recent study, the impact of external force on the strength of Kevlar nanofibers reinforced with silicon dioxide nanoparticles and ethylene glycol was investigated. The findings suggest that optimizing the external force is crucial for an effective collision process.
JOURNAL OF MATERIALS RESEARCH AND TECHNOLOGY-JMR&T
(2023)
Article
Materials Science, Multidisciplinary
Farshad Rahmani, Reza Barbaz-Isfahani, Saeed Saber-Samandari, Manouchehr Salehi
Summary: The aim of this study is to investigate the critical buckling force of a sandwich structure with the addition of nanoparticles to composite faces in an acidic environment. The addition of 3 wt% nanoclay shows better performance in improving the durability of the structure against changes in the length and mass of the composite specimens. The immersion in 5% sulfuric acid for 30 days significantly reduces the critical buckling force of composite sandwiches.
MATERIALS TODAY COMMUNICATIONS
(2023)