Article
Chemistry, Applied
Zhenzhen Yao, Jixin Liu, Xuefei Mao, Guoying Chen, Zhihong Ma, Bingru Li
Summary: For the first time, separation and analysis of Hg2+ and methylmercury was achieved using in-line SPE-LC-AFS. The method was easy, compact, robust, and sensitive in mercury speciation analysis, ensuring food safety.
Article
Chemistry, Analytical
Jinling Pang, Hexun Chen, Xiaojia Huang
Summary: A new method for chromium speciation was proposed by combining magnetism-assisted in-tube solid phase microextraction with high-performance liquid chromatography. The method showed high extraction efficiency for Cr(III) and Cr(VI) complexes, with detection limits of 0.0059 ?g/L and 0.0020 ?g/L in water samples, and 0.47 ?g/kg and 0.057 ?g/kg in soil samples. The successful quantification of trace levels of Cr(III) and Cr(VI) in environmental samples demonstrated the reliability and practicality of the approach.
MICROCHEMICAL JOURNAL
(2021)
Article
Environmental Sciences
Ali Alsalme, Hilal Ahmad, Rais Ahmad Khan, Bon Heun Koo, Ghadah M. M. Alharbi, Shahad I. I. Alhadlaq
Summary: This study chemically introduced thioglycolic acid to improve the selectivity of graphene oxide (GO) nanosheets for metal ion extraction. A solid phase extraction method was developed and optimized, which showed good reliability, accuracy, and low detection limits for arsenic and mercury ions. Real samples were analyzed to validate the established procedure.
Article
Chemistry, Multidisciplinary
Huda Alsaeedi, Hilal Ahmad, Malak Faisal Altowairqi, Nouf AbdulRahman Almuryyi, Ali Alsalme
Summary: A graphene oxide (GO/CdS) nanocomposite was synthesized and used for micro solid phase extraction procedure. The nanocomposite selectively extracts Hg(II) ions from different water samples and shows excellent extraction efficiency. The method has a low detection limit, good accuracy and precision, and has been successfully verified using standard reference materials and real samples.
Article
Chemistry, Analytical
Sergey S. Volynkin, Pavel A. Demakov, Olga V. Shuvaeva, Konstantin A. Kovalenko
Summary: Metal-organic frameworks (MOFs) are increasingly used in analytical chemistry for pre-concentration and determination of trace elements. A new methodology for speciation of inorganic and organic mercury in water was proposed, demonstrating high efficiency, low LODs, wide linear range, and acceptable analysis duration.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Analytical
I. Morales-Benitez, P. Montoro-Leal, J. C. Garcia-Mesa, M. M. Lopez Guerrerp, E. Vereda Alonso
Summary: A novel method for Cr(III) and Cr(VI) speciation in environmental samples was developed using magnetic nanoparticles coupled to graphene oxide. The method combined inductively coupled plasma optical emission spectrometry with on-line magnetic solid phase extraction. The synthesized sorbent material showed good performance with low detection limits and high enrichment factors. The developed method was successfully applied to analyze chromium speciation in environmental water samples, showing good agreement with certified values and high recoveries for spiked samples.
Article
Biochemical Research Methods
Montserrat Mancera-Arteu, Fernando Benavente, Victoria Sanz-Nebot, Estela Gimenez
Summary: In this study, different chromatographic sorbents were evaluated for the analysis of glycopeptides. The PBA sorbent showed the most promising results, leading to the development of a selective and sensitive preconcentration method for glycopeptides. The method was successfully applied to the analysis of recombinant human erythropoietin (rhEPO) and demonstrated improved results compared to previous methods.
JOURNAL OF PROTEOME RESEARCH
(2023)
Article
Chemistry, Analytical
Maria Vergara-Barberan, Ernesto Francisco Simo-Alfonso, Jose Manuel Herrero-Martinez, Fernando Benavente
Summary: An aptamer affinity sorbent was developed for clean-up, preconcentration, separation, and characterization of a food allergen protein. The sorbent, based on magnetic bead particles modified with an aptamer against the target protein concanavalin A, was packed in SPE microcartridges. The developed method showed good linearity, with a low limit of detection, satisfactory repeatability, and the ability to reuse the microcartridges.
MICROCHEMICAL JOURNAL
(2023)
Article
Chemistry, Multidisciplinary
Gurjaspreet Singh, Jashan Deep Kaur, Pawan, Diksha, Sushma, Suman, Shilpy, Pinky Satija, K. N. Singh
Summary: This study demonstrates the design and facile synthesis of 1-adamantanamine-based organosilanes using a click silylation approach. These synthesized organosilanes exhibit preferential selectivity towards Sn2+ ions and can serve as colorimetric/fluorimetric dual-channel probes. The chemosensor 4a shows promising results in the recovery testing of Sn2+ in real soil samples.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Analytical
Yihuan Song, Qingfang Ma, Heyong Cheng, Jinhua Liu, Yuanchao Wang
Summary: A method utilizing online solid-phase extraction coupled with high performance liquid chromatography and inductively coupled plasma mass spectrometry was developed for simultaneous enrichment and analysis of ultra-trace lead and mercury species in water. This method allows for efficient and accurate determination of lead and mercury species in water samples, with high enrichment factors and low LODs and LOQs. The method was successfully applied to analyze trace lead and mercury species in various types of water samples, showing promising results for unstable sample analysis.
ANALYTICA CHIMICA ACTA
(2021)
Article
Chemistry, Analytical
Kamal K. Jinadasa, Paloma Herbello-Hermelo, Elena Pena-Vazquez, Pilar Bermejo-Barrera, Antonio Moreda-Pineiro
Summary: A pre-concentration method for low mercury levels in seaweed was developed, utilizing an imprinted polymer for selective extraction and determination of mercury species. The method showed low detection limits, good repeatability, and was successfully applied to certified reference materials and edible seaweeds for analysis of methylmercury and Hg(II).
Article
Environmental Sciences
Kai-Qiang He, Xiao-Ru Zhang, Yuan-Peng Li, Xue-Lei Duan, Yan Li, Yang-Hong Jiang, Xiao-Dong Yuan, Ke-Gang Zhang, Chun-Gang Yuan
Summary: With the increasing strictness of environmental protection policies in China, coal-fired power plants have widely adopted air pollution control devices, especially selective catalytic reduction (SCR). This study successfully developed an on-line coupling system based on atomic fluorescence spectrometry (AFS) and a homemade chromatographic workstation to identify mercury (Hg) species through thermal programmed desorption (TPD). The main species in fly ash were HgCl2 and HgO, while in gypsum they were Hg2Cl2 and HgO. The study demonstrated that AFS coupled with TPD was an effective method to analyze Hg species in coal combustion by-products from power plants.
Article
Biochemistry & Molecular Biology
Liqin Chen, Yueling Bi, Tong Xu, Xiaohuan Li, Zhongze Fang
Summary: This article introduces two different pretreatment methods for the determination of biogenic monoamines and metabolites in plasma using high performance liquid chromatography. The online PFSPE method stands out due to its greener character and high-throughput compared to the offline PFSPE method.
Article
Chemistry, Analytical
Hiba Salim, Laura Pont, Estela Gimenez, Fernando Benavente
Summary: This study presents an online aptamer affinity solid-phase extraction direct mass spectrometry (AA-SPE-MS) method for the rapid purification, preconcentration, and characterization of alpha-synuclein (alpha-syn), a protein biomarker related to Parkinson's disease. The method utilizes SPE microcartridges and replaces the separation voltage with a pressure of 100 mbar to elute the protein towards the mass spectrometer. The developed method shows good repeatability, satisfactory linearity, and lower limits of detection compared to other techniques.
ANALYTICA CHIMICA ACTA
(2023)
Review
Chemistry, Analytical
Petr Tuma
Summary: This review evaluates the progress made in the past decade in on-line, at-line, and in-line sample treatment coupled with capillary and microchip electrophoresis. The first part discusses various types of flow-gating interfaces (FGI) and their fabrication using materials like polydimethylsiloxane and commercially available fittings. The second part focuses on the coupling of electrophoresis with different extraction techniques, highlighting modern approaches such as supported liquid membrane extraction and microdialysis with high spatial and temporal resolution. The final section explores the design of sequential electrophoretic analyzers and the fabrication of SPE microcartridges with specialized sorbents. Applications of these techniques range from monitoring metabolites and proteins in living organisms to analyzing nutrients and waste compounds in food and wastewater.
ANALYTICA CHIMICA ACTA
(2023)
Article
Chemistry, Analytical
Vanessa de Jesus Ferreira, Jorge S. Almeida, Valfredo A. Lemos, Olivia M. C. de Oliveira, Karina S. Garcia, Leonardo S. G. Teixeira
Summary: A method combining RP-VALLME and EDXRF was developed for the determination of Cu, Mn, Ni, and Pb in diesel oil samples, showing low detection limits, good precision, and high recovery rates. This method proved to be efficient and comparable to ICP-OES for the analysis of the four analytes.
Article
Chemistry, Analytical
Leane Santos Nunes, Maria Gracas Andrade Korn, Valfredo Azevedo Lemos
Summary: A method based on direct-immersion single-drop microextraction was developed for the determination of vanadium in water. The extraction solvent used was the ionic liquid [C6MIM][PF6], and digital images obtained directly from the solvent drop were used for detection. This method showed high sensitivity and accuracy, with minimal sample volume and waste generation, aligning with the principles of green chemistry.
Article
Biotechnology & Applied Microbiology
Ohana Nadine de Almeida, Rebeca Moraes Menezes, Leane Santos Nunes, Valfredo Azevedo Lemos, Francisco Heriberto Martinez Luzardo, Fermin Garcia Velasco
Summary: This study focuses on the Eichornia crassipes plant leaves, transforming them into a solid phase for the determination of lead (II) using flame atomic absorption spectrometry online method. The developed method is a simple, fast, economical, safe, and eco-friendly alternative for lead (II) determination.
ENVIRONMENTAL TECHNOLOGY & INNOVATION
(2021)
Article
Chemistry, Applied
Ravena Souza de Almeida Azevedo, Joao Honorato Santos Neto, Liz Oliveira Dos Santos, Adriano de Araujo Gomes, Debora de Andrade Santana, Ana Maria Pinto Dos Santos
Summary: This study proposes a preliminary assessment of the homogeneity and stability of mechanically processed pumpkin seed meal reference material using digital image acquisition and texture characteristics analysis. The results indicated low homogeneity, with most samples being considered stable.
Article
Chemistry, Applied
Liz O. dos Santos, Ana M. P. dos Santos, Marcia M. C. Ferreira, Sergio L. C. Ferreira, Ana Flavia S. F. Nepomuceno
Summary: A collaborative study was conducted to evaluate laboratory reference material candidates, revealing questionable results from certain laboratories. Multivariate data analysis was shown to be a successful alternative method to ISO guidelines, with defined confidence intervals.
Article
Chemistry, Analytical
Valfredo Azevedo Lemos, Jeferson Alves Barreto, Luana Bastos Santos, Rosivan dos Santos de Assis, Cleber Galvao Novaes, Ricardo J. Cassella
Summary: Dispersive liquid-liquid microextraction (DLLME) is widely used for the separation and preconcentration of various chemical species, with some systems using a syringe as an extraction environment. This review discusses methods utilizing this approach, critical aspects like dispersion promotion, analytical characteristics, and the pros and cons of the methods, as well as future trends in in-syringe microextraction systems.
Article
Chemistry, Analytical
Luana Bastos Santos, Rosivan dos Santos de Assis, Uneliton Neves Silva, Valfredo Azevedo Lemos
Summary: An on-line system using switchable-hydrophilicity solvent-based liquid-phase microextraction for the determination of cobalt in various samples is described in this work. The method is efficient with a detection limit of 0.8 μg L-1 and an enrichment factor of 41. It shows good precision and accuracy when tested with certified reference material. The system is presented as a green and accessible alternative for cobalt determination in analyzed samples.
Review
Chemistry, Analytical
Luana Bastos Santos, Rosivan Santos Assis, Jeferson Alves Barreto, Marcos Almeida Bezerra, Cleber Galvao Novaes, Valfredo Azevedo Lemos
Summary: In recent years, there has been a significant increase in the search for green chemistry principles in analytical methods. Solvents play a crucial role in green analytical chemistry, and certain criteria must be met for a solvent to be considered green, including availability, low toxicity, biodegradability, and low cost. However, the availability of green solvents is currently limited. Deep eutectic solvents (DESs) have emerged as a new and promising alternative to traditional solvents, attracting attention for their eco-friendly, inexpensive, and easily obtainable characteristics. This work provides a critical review of the use of DESs in liquid-phase microextraction (LPME) and their contributions to green chemistry.
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
(2022)
Article
Chemistry, Applied
Sergio Luis Costa Ferreira, Joao Batista Pereira Junior, Danilo Junqueira Leao, Pedro Sanches dos Reis, Adriano Velame Branco Chagas, Liz Oliveira dos Santos
Summary: This study evaluated the mineral composition of red jambo samples collected from 10 cities in Bahia, demonstrating that the fruit is a potential nutritional supplement due to its rich content of various essential elements.
Article
Chemistry, Applied
Joao Honorato Santos Neto, Liz Oliveira dos Santos, Ana Maria Pinto dos Santos, Cleber Galva Novaes, Sergio Luis Costa Ferreira
Summary: This research presents the development, optimization, and application of a low-cost detection system based on digital image analysis for the detection of urea in ultra-high-temperature milk samples. The system shows promising results and can be used to assess the authenticity and quality of milk.
Article
Chemistry, Analytical
Ana Flavia Souto Figueiredo Nepomuceno, Valfredo Azevedo Lemos, Liz Oliveira dos Santos
Summary: A simple, fast, and low-cost method using ultrasonic assisted liquid-phase microextraction and digital imaging colorimetry was developed to determine mefenamic acid in drug samples. The method has a low detection limit and good precision, and follows the principles of green chemistry.
MICROCHEMICAL JOURNAL
(2022)
Article
Hematology
Edvan do Carmo Santos, Paulo Vinicius Bispo Santana, Laine Lopes Silva de Jesus, Gabriela Imbassahy Valentim Melo, Setondji Cocou Modeste Alexandre Yahouedehou, Caroline Conceicao da Guarda, Rayra Pereira Santiago, Luciana Magalhaes Fiuza, Suellen Pinheiro Carvalho, Liz Oliveira dos Santos, Elisangela Vitoria Adorno, Augusto Cezar Magalhaes Aleluia, Luciene Cristina Gastalho Campos Luiz, Teresa Cristina Cardoso Fonseca, Marilda de Souza Goncalves, Milena Magalhaes Aleluia
Summary: Sickle cell disease (SCD) is a condition characterized by the presence of variant S hemoglobin (HbS). Sickle cell anemia (SCA) occurs in individuals with a homozygous genotype (HbSS), while SC hemoglobinopathy refers to individuals with a double heterozygous genotype of HbS and HbC (HbSC). The pathophysiology involves chronic hemolysis, inflammation, endothelial dysfunction, and vaso-occlusion, leading to vascular disease and severe clinical manifestations.
HEMATOLOGY REPORTS
(2023)
Article
Chemistry, Multidisciplinary
Luana B. Santos, Valfredo A. Lemos
Summary: A sensitive method employing vortex-assisted ionic liquid-based liquid-phase microextraction and digital imaging colorimetry is proposed for the determination of antimony species. The method allows for direct determination of Sb-III and measurement of Sb-V by converting it to reduced species. It offers low detection limits, high enrichment factors, and shows good application results in river water and mineral water samples.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
(2022)
Article
Chemistry, Multidisciplinary
Adilson S. Santos, Tereza S. M. Santos, Valfredo A. Lemos, Alexilda O. de Souza
Summary: The study aimed to develop a low-cost and eco-friendly adsorbent from agro-industrial waste for the removal of hexavalent chromium. The adsorbent showed promising potential with a high adsorption capacity and may be a viable and efficient alternative for treating industrial effluents containing trace elements.
JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
(2021)
Article
Chemistry, Analytical
Vanessa Jesus Ferreira, Marina Santos de Jesus, Mayara Costa dos Santos, Wesley N. Guedes, Valfredo A. Lemos, Cleber G. Novaes, Floriatan Santos Costa, Clissiane S. Viana Pacheco, Erik Galvao Paranhos da Silva, Fabio Alan Carqueija Amorim
Summary: A cadmium determination method based on USAEME combined with FAAS was developed in this study, with optimized parameters such as the composition of extraction and dispersive solvents, volume of extraction solvent, pH, and sonication time. The method proved to be simple, fast, and efficient for cadmium determination with small amounts of organic solvents.
ANALYTICAL METHODS
(2021)