4.7 Article

Preparation and sensing performance of petal-like RuO2 modified ZnO nanosheets via a facile solvothermal and calcination method

Journal

TRANSACTIONS OF NONFERROUS METALS SOCIETY OF CHINA
Volume 24, Issue 9, Pages 2896-2903

Publisher

ELSEVIER SCIENCE BV
DOI: 10.1016/S1003-6326(14)63424-5

Keywords

ZnO; RuO2; nanosheets; gas sensing; ethanol; acetone

Funding

  1. National Natural Science Foundation of China [61079010]
  2. Civil Aviation Administration of China
  3. Significant Pre-research Funds of Civil Aviation University of China [3122013P001]
  4. Science and Technology Innovation Guide Funds of Civil Aviation Administration of China

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Petal-like ZnO nanosheets were synthesized with zinc nitrate hexahydrate and sodium hydroxide as starting materials in ammonia and ethanol mixture solution. RuO2 modified ZnO nanosheets were also prepared by a calcination route. The as-prepared products were characterized by X-ray powder diffraction and field emission scanning electron microscopy, and its specific BET surface area was calculated by nitrogen adsorption method. The sensitivity, response and recovery speed were examined. The results show that RuO2 modified petal-like ZnO based sensor exhibits a high sensitivity, a low detection limit, fast response and recovery properties to ethanol and acetone. The sensitivities of the RuO2 modified petal-like ZnO based sensor to 100x10(-6) ethanol and acetone at 360 degrees C are 33 and 67, respectively. The response and recovery times of the sensor are 4 s and 9 s to 10x10(-6) ethanol, and are 3 s and 10 s to 10x10(-6) acetone, respectively.

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