4.4 Article Proceedings Paper

Growth paths for the sulfurization of Cu-rich Cu/In thin films

Journal

THIN SOLID FILMS
Volume 517, Issue 7, Pages 2140-2144

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2008.10.091

Keywords

Growth monitoring; Phase transitions; Thin film; Chalcopyrite; Solar cell

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In-situ energy-dispersive X-ray diffraction performed at the BESSY and HASY-LAB synchrotron facilities was used to observe sulfur pressure dependent growth paths for the formation of CuInS(2) thin films from Cu-rich metallic precursors. CuInS(2) can form directly from the intermetallic phases, through binary sulfides or via CuIn(5)S(8). Particular attention is given to the latter reaction sequence, typical of rapid thermal processing (RTP), with complementary EDS and SEM analysis. (C) 2008 Elsevier B.V. All rights reserved.

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