4.4 Article

Tuning of the flat-band potentials of nanocrystalline TiO2 and SnO2 particles with an outer-shell MgO layer

Journal

THIN SOLID FILMS
Volume 517, Issue 2, Pages 952-956

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2008.07.031

Keywords

Fermi level; TiO2; SnO2; Dye sensitized solar cell; Flat-Band tuning; Flat band potential; Solar cell efficiencies

Funding

  1. National Science Foundation, Sri Lanka [NSF/RG/P/2004/02]

Ask authors/readers for more resources

Flat-Band (FB) potentials of TiO2 and SnO2 nanoparticles shifted negatively once they were coated with a thin insulating MgO layer. For core-shell structured TiO2-MgO and SnO2-MgO composites, incorporation of 1% (w/w) of MgO results in negative shift in FB potential of TiO2 and SnO2 nanoparticles by -0.15 eV and -0.38 eV, respectively. The negative shift of FB increased with the increase of MgO content. The highest shifts in FB potential reached -0.85 eV and -0.65-0.70 eV (vs Standard Calomel Electrode) when MgO content was equal to 10% (w/w) and 10-15% (w/w) for SnO2 and TiO2 respectively. In this investigation, interconnection between the negative shift in FB potential and the efficiencies of dye sensitized solar cells based on the prepared materials are discussed. (C) 2008 Elsevier B.V. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

Article Materials Science, Multidisciplinary

Enhanced catalytic activity of Ni-Mo2C/La2O3-ZrO2 bifunctional catalyst for dry reforming of methane

Qingqing Tao, Zhida Wang, Bandara Jayasundera, Changqing Guo, Yuan Gan, Liang Zhang, Zhuoxin Lu, Hongyi Tan, Changfeng Yan

JOURNAL OF MATERIALS SCIENCE (2018)

Article Acoustics

Sono-photocatalytic production of hydrogen by interface modified metal oxide insulators

Rushdi D. Senevirathne, Lahiru K. Abeykoon, Nuwan L. De Silva, Chang-Feng Yan, Jayasundera Bandara

ULTRASONICS SONOCHEMISTRY (2018)

Article Chemistry, Physical

Superior solar-to-hydrogen energy conversion efficiency by visible light- driven hydrogen production via highly reduced Ti2+/Ti3+ states in a blue titanium dioxide photocatalyst

Nuwan Lakshitha De Silva, A. C. A. Jayasundera, A. Folger, O. Kasian, S. Zhang, Chang-Feng Yan, C. Scheu, J. Bandara

CATALYSIS SCIENCE & TECHNOLOGY (2018)

Article Chemistry, Physical

Piezoelectric materials for catalytic/photocatalytic removal of pollutants: Recent advances and outlook

Zhang Liang, Chang-Feng Yan, Sami Rtimi, Jayasundera Bandara

APPLIED CATALYSIS B-ENVIRONMENTAL (2019)

Article Chemistry, Physical

Removal of groundwater nitrates by heterogeneous supramolecular complexes-like photocatalytic system based on in-situ generated and highly active Ti3+/Ti2+ states in the reduced TiO2

Dulanji S. Dharmagunawardhane, Nuwan L. De Silva, Udara Bimendra Gunatilake, Chang-Feng Yan, Jayasundera Bandara

MOLECULAR CATALYSIS (2019)

Article Chemistry, Physical

Photocatalytic removal of airborne indoor pollutants by IR illuminated silver coated TiO2 catalyst: Advantage of one-dimensional TiO2 nanostructures in IR active photocatalysis

K. M. S. D. B. Kulathunga, Chang-Feng Yan, Jayasundera Bandara

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

Article Energy & Fuels

Enhancement of the photoconversion efficiency of Sb2S3 based solar cell by overall optimization of electron transport, light harvesting and hole transport layers

Mohaiyadeen Aliyar Farhana, Jayasundera Bandara

Summary: In thin-film photovoltaic, Sb2S3 is a leading absorber material and optimizing the electron transport layer, light harvesting layer, and hole transport layer can significantly improve solar cell performance. The precise control of traps, surface defect states, and lattice dislocations in Sb2S3 is crucial for achieving high efficiency.

SOLAR ENERGY (2022)

Article Chemistry, Physical

Harnessing of low-energy IR photons via oxygen-vacancies in SrTiO3 nanocrystals for photocatalytic hydrogen production

Jayasundera Bandara, Chathurika Rajapaksha, C. A. Jayasundera, H. Tan, C. -F. Yan

Summary: Surface-oxygen vacancies were generated to enhance the near-IR light response of SrTiO3 photocatalyst. The hydrogen production rates for SrTiO3-Ov under full solar spectrum, visible and IR radiation were 100, 25 and 10 mlg(-1)h(-1) respectively. The mid-gap Ov and Ti3+ states in SrTiO3-Ov are key factors in the origin of the near-IR responses of the catalyst and the feasibility of using low-photonic-energy IR light to produce hydrogen by water splitting was demonstrated.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2023)

Review Nanoscience & Nanotechnology

Recent advances and new research trends in Sb2S3 thin film based solar cells

Mohaiyadeen Aliyar Farhana, Arumukham Manjceevan, Jayasundera Bandara

Summary: Although many environmentally friendly and non-toxic materials have been investigated for photovoltaic conversion (PVC) applications, Sb2S3 is the preferred material due to its optical response and electrical properties. However, its efficiency is lower than predicted, and this review aims to understand and improve current device performance by studying structural and morphological changes in Sb2S3 thin films. The research discusses the fundamental properties of Sb2S3 and how fabrication techniques and conditions affect solar cell performance.

JOURNAL OF SCIENCE-ADVANCED MATERIALS AND DEVICES (2023)

Article Engineering, Environmental

TiO2 encapsulated cross-linked polystyrene-polyacrylic acid membranes for waste oil-water separation

S. A. D. A. Sumithraarachchi, B. D. K. K. Thilakarathna, Jayasundera Bandara

Summary: Investigation of special wetting materials for oil-water separation showed that enhanced superhydrophobic properties were achieved by cross-linking polystyrene with acrylic acid on TiO2 nanoparticles. The membranes fabricated demonstrated exceptional oil-water separation efficiencies and flux rates due to their excellent oil-wetting properties. It was confirmed that the oil-water separation efficiency, reusability, durability, and hydrophobicity of the membranes can be enhanced through appropriate fabrication methods.

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING (2021)

Article Nanoscience & Nanotechnology

Enhancement of the conversion of mechanical energy into chemical energy by using piezoelectric KNbO3-x with oxygen vacancies as a novel piezocatalyst

Hong-Yi Tan, Liang Zhan, Chang-Feng Yan, Lahiru K. Abeykoon, Nuwan L. De Silva, Jayasundera Bandara

NANO EXPRESS (2020)

Article Chemistry, Multidisciplinary

Modifying Titania Using the Molten-Salt-Assisted Self-Assembly Process for Cadmium Selenide-Quantum Dot-Sensitized Photoanodes

Muammer Y. Yaman, Ahmet Selim Han, Jayasundera Bandara, Cuneyt Karakaya, Omer Dag

ACS OMEGA (2017)

No Data Available