Article
Optics
Meng Kou, Feng Qin, Yongda Wang, Xiyu Zhang, Lu Li, Zheng Hu, Hua Zhao, Zhiguo Zhang
Summary: The effect of excitation power density on K-SV measurement is theoretically analyzed and experimentally studied using PdOEP as an example. The real KSV of PdOEP is determined to be 58 +/- 2 kPa(-1), which is verified through the analysis of oxygen-dependent phosphorescence lifetimes and IP.
Review
Chemistry, Multidisciplinary
Tomasz Koczorowski, Arleta Glowacka-Sobotta, Stepan Sysak, Dariusz T. Mlynarczyk, Roman Lesyk, Tomasz Goslinski, Lukasz Sobotta
Summary: This study gathers and analyzes the latest research results on BODIPY-conjugated metallic nanoparticles, exploring their practicality in the diagnosis and treatment of tumor ailments as well as in sensing of heavy metals, and presents specific examples.
APPLIED SCIENCES-BASEL
(2022)
Article
Chemistry, Physical
Eva Skoura, Peter Bohac, Martin Barlog, Helena Palkova, Andreas Mautner, Larysa Bugyna, Helena Bujdakova, Juraj Bujdak
Summary: The poly(caprolactone) was modified with a thin nanocomposite layer consisting of organoclay and photoactive dye, PhB. Electron microscopy, water contact angle measurements, X-ray diffraction, and various spectroscopies were used to characterize the surface properties and composition of the nanocomposite layer. The films exhibited photoactive and antimicrobial properties.
APPLIED CLAY SCIENCE
(2023)
Article
Materials Science, Ceramics
Alberto Lopez-Grande, Rajesh Dagupati, Pedro Galan del Sastre, Francisco Munoz
Summary: This study investigated the ionic conductivity and structure of lithium phosphate glasses by employing thermodynamic approaches and models such as the associated solutions model, weak electrolyte model, and Anderson and Stuart model. Results showed that these models could accurately predict experimental data, indicating their usefulness in understanding the properties of glasses.
JOURNAL OF THE AMERICAN CERAMIC SOCIETY
(2021)
Article
Chemistry, Analytical
Zhumei Rohskopf, Taehong Kwon, Sung Hee Ko, Dragana Bozinovski, Hyungkook Jeon, Naresh Mohan, Stacy L. Springs, Jongyoon Han
Summary: This study developed a novel nanofluidic system for continuous direct measurement of IgG titers, enabling online monitoring and showing good correlation with biolayer interferometry assays.
ANALYTICAL CHEMISTRY
(2023)
Article
Chemistry, Inorganic & Nuclear
Meng Kou, Yongda Wang, Xiyu Zhang, Hua Zhao, Ye Tian, Feng Qin, Zhiguo Zhang
Summary: This study aimed to quantitatively determine the phosphorescent transition rate in metalloporphyrin and successfully calculated its value through theoretical analysis and experimental results. The findings of this study provide insights into the intrinsic energy characteristics of metalloporphyrins and offer an effective pathway for optimizing their various applications.
INORGANIC CHEMISTRY
(2022)
Article
Energy & Fuels
Ebru Kurtulbas, Ayse Gizem Pekel, Irem Toprakci, Gulsum Ozcelik, Mehmet Bilgin, Selin Sahin
Summary: In this study, a carboxylic acid-based deep eutectic solvent was synthesized and used for removing diclofenac from water. The designed solvent system achieved an approximate 80% removal of diclofenac and was influenced by factors such as initial concentration, solvent level, and temperature.
BIOMASS CONVERSION AND BIOREFINERY
(2022)
Article
Biochemistry & Molecular Biology
Meiyu Jiang, Jiasheng Wu, Weimin Liu, Haohui Ren, Shuai Wang, Pengfei Wang
Summary: Benzopyran nitrile dyes, with low quantum yield of triplet state, are not suitable as qualified photosensitizers. This study successfully prepared a series of selenium-containing photosensitizers using the heavy atom effect, and demonstrated their ability to produce efficient fluorescent signals and light-induced therapeutic effects under laser irradiation. These selenium-containing photosensitizers exhibited excellent biocompatibility and phototoxicity, making them promising agents for NIR fluorescence imaging and photodynamic therapy.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY B-BIOLOGY
(2022)
Article
Pharmacology & Pharmacy
Vladimir Makarov, Daria Pominova, Anastasiya Ryabova, Igor D. Romanishkin, Arina V. Voitova, Rudolf W. Steiner, Victor B. Loschenov
Summary: The study focuses on the biomedical applications of phthalocyanine nanoparticles (AlPc NPs) as nanophotosensitizers. The research discovers that AlPc NPs can enter cells, localize in lysosomes, exhibit fluorescence, and achieve photodynamic therapy.
Article
Chemistry, Multidisciplinary
Ting Yan, Gulinigaer Alimu, Lijun Zhu, Huimin Fan, Linxue Zhang, Zhong Du, Rong Ma, Shuang Chen, Nuernisha Alifu, Xueliang Zhang
Summary: This study developed a novel PDT/PTT nanoparticle for cervical cancer treatment. The nanoparticles exhibited good water solubility and cellular uptake ability, and demonstrated strong PDT/PTT synergistic effect with low cytotoxicity to human cells.
Article
Chemistry, Multidisciplinary
Gaurav Anand, Samira Safaripour, Craig Snoeyink
Summary: This study presents a novel non-electrophoretic, electric field-based separation mechanism that can transport ions based on their dielectric properties. While similar to dielectrophoresis, this polarization-based mechanism is remarkably more efficient at small length scales compared to any dielectrophoretic separation mechanism for particles. The concentration change of the working solute, sodium fluorescein, is shown to decrease by approximately 20% in an electric field region compared to a non-electric field region with an applied electric field strength as low as 0.75 MV m(-1) across a 100 μm channel. Existing macroscopic theoretical models such as electrohydrodynamics and equilibrium thermodynamics underestimate the concentration change by two orders of magnitude for the same electric field strength, suggesting a missing key physics in the electric field-based equilibrium thermodynamic model.
Article
Materials Science, Biomaterials
Kaihang Xue, Feng Wei, Jinyan Lin, Haina Tian, Fukai Zhu, Yang Li, Zhenqing Hou
Summary: The study developed a tumor microenvironment-driven self-targeting nanodrug through assembly guided by ICG, using MTX and PEG for synergistic photothermal-chemotherapy.
BIOMATERIALS SCIENCE
(2021)
Article
Biochemistry & Molecular Biology
Andrea Amadei, Andrea Ciccioli, Antonello Filippi, Caterina Fraschetti, Massimiliano Aschi
Summary: A theoretical-computational procedure based on the quasi-Gaussian entropy theory and molecular dynamics simulations is proposed. It can construct an analytical model of the most relevant thermodynamic properties within a wide temperature range by automatically sampling the entire conformational repertoire of highly flexible systems. The method's reliability mainly depends on the quality of the force field used in the simulations and the ability to distinguish between semi-classical and quantum degrees of freedom in a physically coherent way.
Article
Chemistry, Medicinal
Esther G. Kaye, Karishma Kailass, Oleg Sadovski, Andrew A. Beharry
Summary: In this study, phenalenone derivatives were synthesized with electron-donating groups to red-shift the absorption spectrum, and bromine(s) were added to enhance singlet oxygen production via the heavy-atom effect. Among the derivatives, OE19 showed the longest absorption wavelength, green fluorescence, and efficient singlet oxygen production, demonstrating potential for photodynamic cancer therapy.
ACS MEDICINAL CHEMISTRY LETTERS
(2021)
Article
Biotechnology & Applied Microbiology
Elizaveta I. Kozlikina, Kanamat T. Efendiev, Andrey Yu. Grigoriev, Olesia Y. Bogdanova, Igor S. Trifonov, Vladimir V. Krylov, Victor B. Loschenov
Summary: This paper presents the use of fluorescence diagnostics in the resection of pituitary adenomas. The study used chlorin e6 photosensitizer and a two-channel video system to detect high concentrations of chlorin e6 accumulation in tumor tissues, leading to a high degree of tumor resection.
BIOENGINEERING-BASEL
(2022)