Arrhenius parameters determination in non-isothermal conditions for the uncatalyzed gasification of carbon by carbon dioxide

Non-isothermal thermogravimetric data were used to evaluate the Arrhenius parameters (activation energy, E. and pre-exponential factor, A) for the uncatalyzed gasification by carbon dioxide of two carbons, select as steam activated carbon (BPL) and SP-1 spectroscopically pure graphite. The paper reports on the application of the model-free isoconversional method (KAS/Vyazovkin linear method) for evaluating the activation energy of the gasification process. Activation energies have been calculated by this method were in good agreement with literature data for similar carbons. On the other hand, by means of the kinetic compensation relation between E and In A, which was established by the model-dependent Coats-Redfern method, the value of the pre-exponential factor was estimated from the known value of the model-independent activation energy. (C) 2010 Elsevier B.V. All rights reserved.