4.5 Article

A simple and precise linear integral method for isoconversional data

Journal

THERMOCHIMICA ACTA
Volume 474, Issue 1-2, Pages 81-86

Publisher

ELSEVIER
DOI: 10.1016/j.tca.2008.05.003

Keywords

isoconversional methods; kinetics parameters; Average Method; compensation effect; controlled rate thermal analysis (CRTA); isothermal and non-isothermal kinetics

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A simple and precise linear integral method to evaluate the activation energy dependence oil the extent of conversion has been proposed. The method leads to consistent results with those from differential and integral non-linear procedure (Vyazovkin method). Moreover, the new procedure yields the pre-exponential factor and the kinetic model. The method was evaluated from isothermal, non-isothermal and non-linear non-isothermal data (CRTA). (c) 2008 Elsevier B.V. All rights reserved.

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