Journal
TETRAHEDRON-ASYMMETRY
Volume 24, Issue 8, Pages 505-514Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2013.03.007
Keywords
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Funding
- National Science Centre, Cracow, Poland [03/D/ST5/05766]
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The N-3,5-bis(trifluoromethyl)phenyl thiourea derivative of readily available chiral 1-benzyl-3-aminopyrrolidine was an effective organocatalyst for the asymmetric sulfa-Michael reaction. The adducts of aliphatic thiols to nitro olefins and nitrodienes were formed in good yields and with up to 87% ee in the presence of 2.5 mol % of the organocatalyst. (C) 2013 Elsevier Ltd. All rights reserved.
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