Journal
TETRAHEDRON-ASYMMETRY
Volume 22, Issue 1, Pages 36-39Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.11.026
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The iridium-catalyzed asymmetric hydrogenation of N-phenyl-beta-dehydroamino acid derivatives was examined using monodentate phosphoramidite ligands. The highest yields and enantioselectivities were obtained using a mixed ligand approach with PipPhos L1 and achiral triphenylphosphine (full conversion, 70% ee). (C) 2010 Elsevier Ltd. All rights reserved.
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