Journal
TETRAHEDRON-ASYMMETRY
Volume 22, Issue 5, Pages 575-579Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.02.031
Keywords
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Funding
- NSFC [20872139, 21072186]
- West Light Foundation of CAS
- National Basic Research Program of China (973 Program) [2010CB833300]
- Chengdu Institute of Biology, CAS [Y0B1051100]
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A class of novel chiral SO-S-type bidentate ligands based on the tert-butylsulfinyl moiety as the sole chiral source were designed and synthesized through a simple and efficient pathway. These ligands are effective catalyst precursors for the palladium-catalyzed allylic alkylation of 1,3-diphenyl-2-propenyl acetate and moderate to good stereoselectivities (up to 84% ee) were obtained. (C) 2011 Elsevier Ltd. All rights reserved.
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