Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 18, Pages 2295-2301Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.07.032
Keywords
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Funding
- UKZN
- SA/Swedish research links programme [65387]
- Aspen pharmacare, SA
- NRF
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A novel family of tetrahydroisoquinoline (TIQ) phosphine-oxazoline ligands and four corresponding iridium complexes have been developed and applied to the asymmetric hydrogenation of unfunctionalized olefins. The results showed that the best conversion rates were observed in up to 99% with an enantiomeric excess of 91%. (C) 2010 Elsevier Ltd. All rights reserved.
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