Journal
TETRAHEDRON-ASYMMETRY
Volume 21, Issue 11-12, Pages 1406-1410Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.04.031
Keywords
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Funding
- MUR [2007HMTJWP]
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Monodentate binaphthophosphepines (BINEPINES) have been tested in the palladium-catalyzed asymmetric allylic alkylation of 1,3-diphenylallyl esters. Stereoselectivities of up to 92% ee have been achieved in the alkylation of the acetate ester with the C-nucleophile, generated in situ by the action of BSA (N,O-bis(trimethylsilyl)acetamide) on dimethylmalonate in the presence of a catalytic amount of sodium acetate. (C) 2010 Elsevier Ltd. All rights reserved.
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