Journal
TETRAHEDRON-ASYMMETRY
Volume 19, Issue 21, Pages 2492-2496Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2008.10.019
Keywords
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Funding
- Scientific Research on Priority Areas 'Advanced Molecular Transformation of Carbon Resources'
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
- Materials Analysis Center of ISIR
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An efficient synthetic method for chiral (isoxazole-isoxazoline) ligands based on a spiro[4.5]decane framework has been developed. A variety of enantiomerically pure ligands were readily prepared via the Suzuki-Miyaura coupling. The palladium complexes of these ligands have proven to be effective catalysts for the asymmetric Wacker-type cyclization of an alkenyl alcohol. (C) 2008 Elsevier Ltd. All rights reserved.
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