Journal
TETRAHEDRON LETTERS
Volume 55, Issue 52, Pages 7233-7235Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.11.034
Keywords
Alkylation; Solvent-free; C-C coupling; Iridium complexes; Dehydrogenation aldol condensation
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Funding
- National Natural Science Foundation of China [21401080, 21371080]
- Natural Science Foundation of Jiangsu Province of China [BK20130125]
- China Postdoctoral Science Foundation [2014M550262]
- MOE & SAFEA for the 111 Project [B13025]
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The alpha-allcylation of ketones with primary alcohols was realized by C-C cross-coupling with iridium-CNP complexes as catalyst. This reaction proceeds via dehydrogenation reactions, aldol condensation, and hydrogenation using the borrowed hydrogen atoms from alcohols. The pyridyl methanols and other heterocyclic substituted methanols, especially alkyl alcohols, were also suitable for this transformation. (C) 2014 Elsevier Ltd. All rights reserved.
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