Journal
TETRAHEDRON LETTERS
Volume 55, Issue 29, Pages 3920-3922Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.05.022
Keywords
Cannizzaro reaction; Catalytic promiscuity; Novozyme 435; Organic reaction in aqueous media
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Funding
- Department of Science and Technology (DST), Govt. of India [SR/SO/BB-68/2010]
- CSIR, India
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Lipases were found to catalyze Cannizzaro-type reaction of substituted benzaldehydes in aqueous medium at 30 degrees C without the addition of any external redox reagent. The ratio of alcohol product to acid product varied with nature of the substituted benzaldehyde, enzyme, and the presence of organic co-solvent. (C) 2014 Elsevier Ltd. All rights reserved.
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