Article
Chemistry, Inorganic & Nuclear
Anthonisamy Roniboss, Ramdas Nishanth Rao, Kaushik Chanda, M. M. Balamurali
Summary: Three model hydrazide derivatives were synthesized and studied for their ability to sense various anions, with benzohydrazide showing the ability to detect both CN- and F- ions. The sensing mechanism may involve deprotonation of the N-H moiety in the hydrazides.
INORGANIC CHEMISTRY COMMUNICATIONS
(2021)
Article
Chemistry, Applied
Seungjoo Baek, Mohammed Iqbal Khazi, Jong-Man Kim
Summary: Chemical sensors based on stimulus-responsive chromogenic materials are important for their ability to manipulate optical properties and display vivid colors. In this study, a chromogenic poly-diacetylene (PDA) was generated through polymerization of protonated supramolecular assemblies of a diacetylene precursor. The PDA exhibited a blue color and showed a sensory response to ammonia, transitioning from blue to red and emitting fluorescence upon deprotonation. The self-assembly behavior, topochemical polymerization, and ammonia sensing properties were investigated using spectroscopic methods.
Article
Nanoscience & Nanotechnology
Gopal Ammanath, Carla Giorgia Delachi, Soner Karabacak, Yusuf Ali, Bernhard O. Boehm, Umit Hakan Yildiz, Palaniappan Alagappan, Bo Liedberg
Summary: A simple method for colorimetric and fluorometric profiling of AGEs was reported in this study, utilizing changes in optical properties of PTs and Apts to estimate the concentrations of AGEs in plasma, and achieving distinct profiling of different AGEs through PCA analysis. The approach allows for rapid analysis of spiked AGEs in plasma samples without the need for preanalytical processing and advanced instrumentation, facilitating on-site diagnosis.
ACS APPLIED MATERIALS & INTERFACES
(2022)
Article
Chemistry, Physical
Mujthaba A. Aatif, S. K. Ashok Kumar
Summary: The newly designed quinoline acrylonitrile probe L exhibits selective colorimetric response towards AsO2- and turn-on emission fluorescent with CN-, forming 1:1 complex with both ions. It can work within a specific pH range, with high sensitivity towards AsO2- and CN-.
JOURNAL OF MOLECULAR STRUCTURE
(2022)
Article
Chemistry, Physical
Efdal Teknikel, Canan Unaleroglu
Summary: The usability of BrBDP in colorimetric/fluorimetric determination, discrimination, and quantification was investigated, revealing its ability to distinguish amines based on their structural properties. The chemodosimeter showed high selectivity towards tested functional groups and could be used for detecting volatile amines. Furthermore, it was proven to be effective in detecting biogenic amines released from spoiled chicken meat.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2022)
Article
Biochemistry & Molecular Biology
Shrishti P. Pandey, Pamela Jha, Prabhat K. Singh
Summary: The study developed a fluorescence probe TO for efficient colorimetric and fluorimetric detection of Heparin, with detection limits of 19nM and 34nM respectively, and also applicable for detecting Protamine in complex detection. The sensing system showed advantages of simplicity, economic benefits, and specific detection of Heparin.
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
(2021)
Article
Chemistry, Applied
Dilek Ozturk, Ipek Omeroglu, Baybars Koksoy, Cem Gol, Mahmut Durmus
Summary: In this study, two novel BODIPY compounds were synthesized and used to construct colorimetric and fluorometric paper-based pH sensors. The compounds were characterized using various analysis techniques, and their properties and performances were determined. Additionally, a simple and reliable method was developed for detecting pH changes in lemon juice.
Article
Chemistry, Multidisciplinary
Shu-Wei Chen, Xipeng Chen, Yang Li, Yalin Yang, Yuchuan Dong, Jinwen Guo, Jinyi Wang
Summary: The development of novel sensors for the detection of lead ions has attracted increasing interest due to their toxic effects on human health and the environment. In this study, two new polydiacetylene-based liposome sensors were developed for the colorimetric and fluorometric recognition of lead ions in aqueous solution. These sensors exhibited high selectivity and sensitivity, and were successfully applied to detect trace amounts of lead ions in real water samples.
Article
Nanoscience & Nanotechnology
Mohamed R. Elmasry, Samy M. Shaban, Ahmed Y. Elbalaawy, Eslam Hafez, Jihoon Shin, Soo-Yeon Cho, Dong-Hwan Kim
Summary: In this study, a dual-signal nanosensor was designed for rapid and accurate urea detection using fluorescent carbon dot nanosensors and plasmonic silver nanoparticles. The sensor showed low detection limits and reliable performance in real urine samples.
ACS APPLIED NANO MATERIALS
(2023)
Article
Chemistry, Physical
Parvathy O. Chandrasekaran, Ajayakumar Aswathy, Kiran James, Kannankutty Kala, Mohanan T. Ragi, Narayanapillai Manoj
Summary: In this study, a molecular chameleon with D-pi-A architecture, PRAA, was synthesized and utilized as a fluorescent sensor for toxic metal ions. Its selectivity towards Ag+, Hg2+, and Pb2+ ions can be adjusted by solvent polarity. The mechanism of binding and stoichiometry of interaction were established through experimental and theoretical methods. PRAA's potential as a probe for detecting Ag+ and Hg2+ ions in aqueous solutions using an anionic surfactant medium was convincingly demonstrated.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2021)
Article
Chemistry, Multidisciplinary
Yuan-Tao Huang, Min Xue, Yong Yang
Summary: The tetra(amino)azacalix[4]arene skeleton was functionalized using various aromatic aldehydes, resulting in the formation of imidazobenzimidazole fused heterocycles. Anthracenyl and pyrenyl modified imidazobenzimidazole fused azacalix[4]arenes existed as dimers in the solid state, while the tetrapyrenyl modified product served as a Zn2+-selective sensor.
CHINESE CHEMICAL LETTERS
(2023)
Article
Chemistry, Analytical
Serkan Erdemir, Sait Malkondu
Summary: Cyanide, a highly toxic chemical mainly released from industrial production, requires selective, sensitive, and rapid monitoring techniques for detection. The efficient cyanide probe reported in this study, based on thiazolium conjugated HBT-Br derivative, shows significant color change towards cyanide under different lighting conditions. Through ESIPT and ICT processes, the probe can effectively detect cyanide at levels lower than physiologically lethal concentrations.
Article
Spectroscopy
Qinghua Wu, Shengyuan Wang, Erhong Hao, Lijuan Jiao
Summary: Two beta-formylBODIPYs show strong daylight excitable fluorescence and highly selective responses to cyanide anion. Surprisingly, cyanide anion undergoes nucleophilic addition to the alpha-position of the BODIPY core instead of the expected formyl moiety, causing interruption of pi-conjugation and significant blue-shift of absorption maxima.
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY
(2021)
Article
Chemistry, Physical
Selin Manoj Kumar, Dhanapal Jothi, Sathishkumar Munusamy, Saravanan Enbanathan, Sathiyanarayanan Kulathu Iyer
Summary: In this study, a new sensor BMA was designed, which exhibited tremendous colorimetric and fluorometric behavior towards CN- ions. The cyanide recognition mechanism of BMA was verified by optical experiments and structural characterization. The sensor BMA showed rapid response, low detection limit, good pH stability, sensitivity, and selectivity towards CN- ions.
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
(2023)
Review
Chemistry, Multidisciplinary
Saikat Kumar Manna, Sanchita Mondal, Barnali Jana, Khokan Samanta
Summary: This review provides an overview of the development of chemosensors for tin ions, with a focus on Sn4+ and Sn2+. Comparison data, future opportunities, and current issues are also discussed.
NEW JOURNAL OF CHEMISTRY
(2022)
Article
Chemistry, Organic
Geeta Devi Yadav, Pooja Chaudhary, Balaram Pani, Surendra Singh
Summary: Chiral transition metal complexes with privileged ligands are efficient catalysts for various asymmetric organic transformations. Transition metal complexes of C1-symmetric pyrrolidine-based ligands have been widely used in asymmetric organic reactions. However, a comprehensive review article on the transition metal complexes of chiral C1-symmetric pyrrolidine-based ligands derived from (L)-proline has not been published.
TETRAHEDRON LETTERS
(2024)
