Journal
TETRAHEDRON LETTERS
Volume 54, Issue 2, Pages 192-194Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.10.124
Keywords
Sattazolin; Antiviral; Indole acyloin; Natural product
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Funding
- Fort Lewis College
- Research Corporation for Science Advancement
- Division Of Undergraduate Education
- Direct For Education and Human Resources [1068341] Funding Source: National Science Foundation
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The first asymmetric total synthesis of the antiviral natural product (+)-sattazolin is reported. The total synthesis allowed for unambiguous assignment of the absolute configuration of the hydroxyl bearing stereocenter. Strategies to circumvent an unanticipated alpha-ketol rearrangement encountered in the final steps are also outlined. (C) 2012 Elsevier Ltd. All rights reserved.
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