Journal
TETRAHEDRON LETTERS
Volume 54, Issue 52, Pages 7171-7174Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.10.107
Keywords
Caged; Caged glutamate; Photolysis; Bond cleavage; TPA
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [24109008, 21108516, 19350021]
- Tokuyama Science Foundation
- Grants-in-Aid for Scientific Research [21108516] Funding Source: KAKEN
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'Caging' and 'uncaging' bioactive substrates are key techniques in studying a wide variety of biological processes. In the present study, two-types of novel caged glutamates with a two-photon absorption (TPA) core, that is, pi-extended coumarin, were synthesized and their photochemical release of glutamate was analyzed. The high yields of glutamate (>92%) were observed in the photolysis of compounds 1 and 10, respectively. (C) 2013 Elsevier Ltd. All rights reserved.
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