Journal
TETRAHEDRON LETTERS
Volume 54, Issue 12, Pages 1593-1595Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.01.048
Keywords
Huperminone A; Huperzia phlegmaria; Lycopodium phlegmaria; Lycopodium alkaloid
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology of Japan
- The Open Research Center Project
- HIR UM-MOHE [F000009-21001]
- Grants-in-Aid for Scientific Research [25460139] Funding Source: KAKEN
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A novel C16N-type Lycopodium alkaloid consisting of a decahydroquinoline and a cyclohexanone, huperminone A (1), was isolated from the club moss of Huperzia phlegmaria, and the structure and relative stereochemistry were elucidated on the basis of spectroscopic data. This unique C16N-type skeleton lacking in a nitrogen atom may be generated from C16N2-type phlegmarane skeleton. (c) 2013 Elsevier Ltd. All rights reserved.
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