4.4 Article

Highly efficient oxidation of benzyl alcohols using the catalytic system sulfoxide/oxo-complexes

Journal

TETRAHEDRON LETTERS
Volume 53, Issue 46, Pages 6205-6208

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.08.145

Keywords

Oxidation; Benzyl alcohols; Aldehydes; Oxo-complexes; Sulfoxides

Funding

  1. FCT [PTDC/QUI-QUI/110080/2009, SFRH/BD/63471/2009]
  2. [PEst-OE/QUI/UI0100/2011]
  3. Fundação para a Ciência e a Tecnologia [PEst-OE/QUI/UI0100/2011, SFRH/BD/63471/2009] Funding Source: FCT

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This work reports a novel and highly efficient method for the oxidation of benzyl alcohols to the corresponding aldehydes catalyzed by HReO4 (5 mol %) using 4-methylphenyl sulfoxide as the oxidizing agent. (C) 2012 Elsevier Ltd. All rights reserved.

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