4.4 Article

Highly practical boronic acid surrogates for the Suzuki-Miyaura cross-coupling

Journal

TETRAHEDRON LETTERS
Volume 52, Issue 10, Pages 1132-1135

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.01.012

Keywords

Palladium; Cross-coupling; Biaryls; Boron; Catalysis

Funding

  1. Minakem
  2. France Alzheimer Association
  3. Region Midi Pyrenees [APRTCN 09004783]
  4. CNRS
  5. University Paul Sabatier

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Boronic acids and esters are well known substrates for the Suzuki-Miyaura cross-coupling. Yet their isolation can sometimes be tedious. We report here that the use of aryl dioxazaborocanes afford a simple isolation procedure while keeping a high efficiency in the cross-coupling process. (C) 2011 Published by Elsevier Ltd.

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