Journal
TETRAHEDRON LETTERS
Volume 52, Issue 41, Pages 5217-5219Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.07.114
Keywords
Homoallylic alcohol; Isomerization; Allylic alcohol; Aminopalladation
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According to experimental and literature data, the one-pot formation of allylic azides or sulfonamides from catalytic amounts of PdCl2, homoallylic alcohols and TMSN3 or TsNH2 occurs through C=C migration followed by regioselective nucleophilic addition on the Pd-II-activated C=C bond and beta-OH elimination. (C) 2011 Elsevier Ltd. All rights reserved.
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