4.4 Article

Rapid and selective oxidation of benzyl alcohols to aldehydes and ketones with novel vanadium polyoxometalate under solvent-free conditions

Journal

TETRAHEDRON LETTERS
Volume 52, Issue 20, Pages 2563-2565

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.03.044

Keywords

Polyoxometalate; Oxidation; Benzylic alcohol; Solvent-free; Vanadium

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A novel vanadium polyoxometalate [(C6H5CH2)(CH3)(3)N](3)[H3V10O28]3H(2)O works as a useful oxidant for selective and rapid oxidation of benzylic alcohols to the corresponding carbonyl compounds in the presence of PTSA under solvent-free, room temperature in excellent yield. (C) 2011 Elsevier Ltd. All rights reserved.

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