4.4 Article

Synthesis and properties of cyclic ethylene-bridged 3,6-fluorene dimer and its linear analogues

Journal

TETRAHEDRON LETTERS
Volume 51, Issue 37, Pages 4894-4897

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.07.064

Keywords

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Funding

  1. Natural Science Foundation of China
  2. State Key Basic Research Program
  3. Chinese Academy of Sciences

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Three oligomers of ethylene-bridged 3,6-fluorene were synthesized starting from phenanthrenequinone. McMurry reaction was applied to synthesize the cyclic compound. Horner-Emmons reaction was used to synthesize the linear compounds with all-trans configuration. The crystal structure of the cyclic compound was described. The optical and electronic properties of these compounds were fully characterized and compared. (C) 2010 Elsevier Ltd. All rights reserved.

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