4.4 Article

Functional polypyridine ligands from copper-mediated room temperature coupling of 4-chloro-2-trimethylsilylpyridine

Journal

TETRAHEDRON LETTERS
Volume 51, Issue 27, Pages 3558-3560

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.04.133

Keywords

Trimethylsilylpyridine; Copper; Cross-coupling; Homocoupling; Polypyridines

Funding

  1. CNRS
  2. French Ministry of Research

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A range of functional polypyridine ligands (bipyridines and terpyridine) has been synthesized by copper-mediated oxidative homocoupling of 4-chloro-2-trimethylsilylpyridine or cross-coupling with functional bromopyridines. The reaction proceeded smoothly at room temperature. (C) 2010 Elsevier Ltd. All rights reserved.

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