4.4 Article

Palladium-catalyzed hydrophenoxycarbonylation of internal alkynes by phenol and CO: the use of Zn for the formation of active catalyst

Journal

TETRAHEDRON LETTERS
Volume 51, Issue 52, Pages 6818-6821

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.10.017

Keywords

Carbon monoxide; Internal alkyne; Phenol; Reppe carbonylation; Zn powder

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The palladium-catalyzed hydrophenoxycarbonylation of internal alkynes by phenol and carbon monoxide was successfully realized by Pd(OAc)(2)/dppp catalyst system in the co-presence of Zn dust. (C) 2010 Elsevier Ltd. All rights reserved.

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