4.4 Article

'Click' synthesis of ferrocenyl-, biferrocenyl-, and cobalticenyl-triazolyl-β-cyclodextrins

Journal

TETRAHEDRON LETTERS
Volume 51, Issue 35, Pages 4617-4619

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.06.115

Keywords

Ferrocene; Cobalticinium; Alkyne; Cyclodextrin; Click reaction; Redox

Funding

  1. Universities Bordeaux 1 and Artois
  2. Centre National de la Recherche Scientifique
  3. Agence Nationale pour la Recherche [ANR-07-CP2D-05-01]

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Cu-I-catalyzed Huisgen-type dipolar 'click' reactions between azidomethyl-beta-cyclodextrin and ethynylferrocene, ethylnylcobaltocenium hexafluorophosphate, and bis(ethynyl)-biferrocene yield the corresponding metallocenyl-1,2,3-triazolyl-beta-cyclodextrins. The monometallocenyl 1,2,3- triazolyl-beta-cyclodextrins are soluble in water, unlike the biferrocene derivative. (C) 2010 Elsevier Ltd. All rights reserved.

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