Journal
TETRAHEDRON LETTERS
Volume 51, Issue 28, Pages 3626-3628Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.05.011
Keywords
Suzuki cross-coupling; Diarylacetylene; Palladium chloride; Alkynylation
Categories
Funding
- Ministry of Science and Technology of China
- Chinese National Natural Science Foundation [20633020, 20672017]
- National Basic Research Program of China [2009CB220009]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0711]
- K & A Wallenberg Foundation
- Swedish Energy Agency
- Swedish Research Council
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Anew Suzuki-type cross-coupling reaction between 1-iodo-2-arylalkynes and arylboronic acids to afford a wide variety of functionalized diarylacetylenes in a mild reaction condition was developed. The reaction was catalyzed by a small amount of a structurally simple, commercially available, and stable PdCl2. This unique sp-sp(2) carbon-carbon bond formation provides a new protocol for the synthesis of diarylacetylenes, which is a new addition to the Suzuki cross-coupling reaction. (C) 2010 Elsevier Ltd. All rights reserved.
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