Journal
TETRAHEDRON LETTERS
Volume 50, Issue 34, Pages 4934-4936Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.06.063
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A novel method to enable asymmetric reduction of ketones by an alcohol dehydrogenase from Geotrichum candidum in a supercritical carbon dioxide and water biphasic system is described. The addition of sodium bicarbonate improved the reactivity up to a practical level while retaining excellent enantioselectivity. (C) 2009 Elsevier Ltd. All rights reserved.
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