Journal
TETRAHEDRON LETTERS
Volume 50, Issue 26, Pages 3585-3587Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.03.046
Keywords
Oxygen transfer; Carbonyl oxide; Metalloporphyrin; Active oxygen species
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The reaction of singlet oxygen with diazofluorene in the presence of metalloporphyrin caused oxidation of hydrocarbons as well as Sulfide and anisol in substantial yields. The active oxidizing species is probably a high valency metal oxo species(M=O(porph)Cl) generated by an oxygen transfer from carbonyl oxide intermediate to M(porph)Cl. (C) 2009 Elsevier Ltd. All rights reserved.
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