Journal
TETRAHEDRON LETTERS
Volume 50, Issue 26, Pages 3568-3570Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.03.025
Keywords
Rhodium carbenoid; Wolff rearrangement; Ketal; Lactone; Ketene
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Funding
- Commonwealth Scholarship Commission [NGCA-2006-64]
- University of Benin, Nigeria
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Treatment of pyruvate ketal-derived diazoacetoacetates or vinyldiazoketones with rhodium(II) complexes at elevated temperatures results in an Unusual skeletal rearrangement to afford eight-membered ring lactones. (C) 2009 Elsevier Ltd. All rights reserved.
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