Journal
TETRAHEDRON LETTERS
Volume 49, Issue 17, Pages 2768-2771Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.02.131
Keywords
biocatalytic transformation; carrot root; enantioselective reduction; chiral tetrahydropyranols
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Enzymatic reduction of 2-substituted tetrahydropyran-4-ones with Daucus carota, plant cells as biocatalyst occurred in water under extremely mild and environmentally benign conditions giving a 1:1 mixture of diastereoselectively (2R,4S)- and (2S,4S)-2-aryl- or 2-alkyl-tetrahydropyranois in high yields. (c) 2008 Published by Elsevier Ltd.
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