4.4 Article

Intermolecular asymmetric cyclopropanation with diazoketones catalyzed by chiral ruthenium porphyrins

Journal

TETRAHEDRON LETTERS
Volume 49, Issue 13, Pages 2111-2113

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2008.01.129

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The asymmetric addition of diazoacetophenone to styrene derivatives to give optically active cyclopropyl ketones (ee up to 86%) was carried out by using chiral ruthenium porphyrins as homogeneous catalysts. (C) 2008 Elsevier Ltd. All rights reserved.

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