Journal
TETRAHEDRON LETTERS
Volume 49, Issue 3, Pages 500-503Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2007.11.097
Keywords
titanocene monochloride; radical cyclization; allene; multifunctional tetrahydrofurans
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Ti(III)-mediated intramolecular free radical cyclization of epoxyallene ethers in an exo-mode was studied. The reaction afforded an efficient and highly regioselective method of synthetically important 3-vinyl-4-hydroxymethyl tetrahydrofurans. (C) 2007 Elsevier Ltd. All rights reserved.
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