Journal
TETRAHEDRON
Volume 70, Issue 31, Pages 4657-4660Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2014.05.029
Keywords
1,2,4-Triazoloquinoxaline; One-pot synthesis; Transition metal-free; Broad range of substrates
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Funding
- National Science Foundation of China [21172131]
- State Key Laboratory of Bioactive Substance and Function of Natural Medicines
- Institute of Materia Medica
- Chinese Academy of Medical Sciences
- Peking Union Medical College [GTZK201405]
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A transition metal-free tandem process for the synthesis of 1,2,4-triazoloquinoxalines was described. The construction of this tricyclic system went through a one-pot condensation/nucleophilic aromatic substitution approach. This methodology applied to a broad range of substrates, which included 2-halogenated or 2-nitro aryl aldehydes and ketones. (C) 2014 Elsevier Ltd. All rights reserved.
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