4.4 Article

An efficient catalytic method for fulvene synthesis

Journal

TETRAHEDRON
Volume 67, Issue 45, Pages 8607-8614

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.09.036

Keywords

Fulvenes; LFER studies; Green synthesis; Catalysis; Cyclopentadiene

Funding

  1. National Institutes of Health [1SC1GM082340]
  2. Turkish Scientific and Technological Research Council (TUBITAK) [BIDEP-2219]
  3. National Science Foundation [DBI-0521342, DUE-9451624]

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The effects of the nature and amount of base, substrate structure, amount of added water and solvent on the condensation of carbonyl compounds with cyclopentadiene in the presence of secondary amines were investigated. Based on these studies, a new efficient and green synthesis of fulvenes was developed. (C) 2011 Elsevier Ltd. All rights reserved.

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