Journal
TETRAHEDRON
Volume 67, Issue 33, Pages 6036-6044Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.06.032
Keywords
Cyclopeptide; Quaternary amino-acid
Categories
Funding
- Rhodia
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We describe the conception, synthesis, and characterization of a novel cyclopeptide designed for chiral recognition. The asymmetric units are built from an unnatural amino acid in the series of alpha-aryl-alpha-methyl glycine. Modifications of standard methods of peptide synthesis are described in order to improve yields and purities when applied to hindered amino acids. First set of experiments about host-guest ability of the obtained cyclopeptide is disclosed. (C) 2011 Elsevier Ltd. All rights reserved.
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