Journal
TETRAHEDRON
Volume 67, Issue 52, Pages 10097-10104Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.09.088
Keywords
Welwitindolinones; Vilsmeier-Haack reaction; O-Acylation; Chlorination; Aromatic Cope rearrangement
Categories
Funding
- National Cancer Institute of the NIH [R01 CA101438]
- American Cancer Society [PF-04-016-01-CDD]
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We recount several unexpected results observed in the course of our work toward the synthesis of welwitindolinone alkaloids. The surprising results provide an opportunity to refine one's understanding of the interplay between chemical structure and reactivity. (C) 2011 Elsevier Ltd. All rights reserved.
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