Journal
TETRAHEDRON
Volume 67, Issue 17, Pages 3111-3118Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2011.02.074
Keywords
Tetrathiomolybdate; Sulfamidates; Burgess reagent; Amino thiols
Categories
Funding
- CSIR, New Delhi
- DST, New Delhi
Ask authors/readers for more resources
Herein we present a simple and highly efficient method for the synthesis of beta and gamma-amino thiols via regioselective ring opening of sulfamidates with tetrathiomolybdate 1. The generality of this methodology has been shown by synthesizing carbohydrate derived beta-amino thiol. The scope and versatility of this methodology has been demonstrated by synthesizing biologically important unnatural amino acids like isocysteines in optically pure form. (C) 2011 Elsevier Ltd. All rights reserved.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available