Journal
TETRAHEDRON
Volume 66, Issue 34, Pages 6885-6888Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2010.06.054
Keywords
Cycloalumination; Cyclomagnesiation cyclic alkynes; Zr complexes; Homogeneous catalysis; Macrocyclic ketones; Ozonolysis
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Funding
- Russian Foundation for Basic Research [10-03-00046]
- RF [MC-1039.2007.3, Sci.Sh.-2349.2008.3]
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A new effective method for designing unique gigantic polyfunctional macrocarbocycles from cyclic acetylenes and Grignard reagents through the catalytic cyclometalation reaction in the presence of transition metal based complexes has been elaborated. (C) 2010 Elsevier Ltd. All rights reserved.
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