4.4 Article

Light-fluorous TEMPO: reagent, spin trap and stable free radical

Journal

TETRAHEDRON
Volume 65, Issue 27, Pages 5271-5277

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.04.078

Keywords

Fluorous-TEMPO; Fluorous solid-phase extraction; ESR spectra; Oxidation reaction; Radical spin trap

Funding

  1. EPSRC National Mass Spectrometry Service (Swansea, UK)

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The synthesis of two light-fluorous TEMPO derivatives is reported, along with their fluorous-organic solvent partition coefficients and their ESR spectra. Applications of the fluorous-TEMPO reagents in oxidation reactions and as radical traps are discussed. (C) 2009 Elsevier Ltd. All rights reserved.

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