4.4 Article

Cyclic 1,1-bis(silyl)alkenes-new building blocks for the stereoselective synthesis of unsymmetrical (E)-stilbenes and (E,E)-1,4-diarylbuta-1,3-dienes

Journal

TETRAHEDRON
Volume 65, Issue 28, Pages 5497-5502

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.01.113

Keywords

Bis(silyl)alkene; C-C bond formations; Heck coupling; Hiyama coupling

Funding

  1. Ministry of Science and Higher Education (Poland) [NN 204 238734, PBZ KBN 118/T09/17]

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A new efficient synthetic protocol for the highly stereoselective synthesis Of Unsymmetrical (or symmetrical) (E)-stilbenes and (E,E)-1,4-diarylbuta-1,3-dienes based on sequential palladium-catalyzed Heck arylation-Hiyama cross-coupling reactions using cyclic gem-bis(silyl)ethene as alkenyl building block is reported. (C) 2009 Elsevier Ltd. All rights reserved.

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