Journal
TETRAHEDRON
Volume 65, Issue 26, Pages 5093-5101Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tet.2009.02.047
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Funding
- JSPS [20675002, 19350046, 19028015]
- MEXT
- Grants-in-Aid for Scientific Research [20675002, 19350046, 19028015] Funding Source: KAKEN
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A cationic rhodium(I)/BINAP complex catalyzes partial intramolecular [2+2+2] cycloadditions of 1,6- and 1,7-diynes with enol ethers or a ketene acetal giving substituted benzenes in good yields. The same catalyst also catalyzes complete intermolecular [2+2+2] cycloadditions of two different monoynes with enol acetates giving tri- and tetrasubstituted benzenes in good yields with complete regioselectivity. Commercially available liquid enol ethers and acetates can be used as versatile equivalents for gaseous alkynes in the present rhodium-catalyzed formal cross-alkyne cyclotrimerizations. (C) 2009 Elsevier Ltd. All rights reserved.
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