4.0 Article

Trivalent zirconium and hafnium ions in yttria-based transparent ceramics

Journal

TECHNICAL PHYSICS LETTERS
Volume 39, Issue 4, Pages 377-379

Publisher

MAIK NAUKA/INTERPERIODICA/SPRINGER
DOI: 10.1134/S1063785013040214

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Funding

  1. Presidium of the Russian Academy of Sciences [12-P-2-1011]
  2. Presidium of the Ural Branch of the Russian Academy of Sciences [12-2-003-YaTs]
  3. Russian Foundation for Basic Research [13-08-00159]

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Electron paramagnetic resonance spectra of transparent yttria-based ceramics with zirconium and hafnium additives contain signals with close parameters due to paramagnetic Zr3+ and Hf3+ ions, which have similar ground-state electron configurations of [Kr]4d (1) and [Xe]5d (1), respectively.

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